4.7 Article

Are Onsager's reciprocal relations necessary to apply Thermodynamic Extremal Principles?

期刊

出版社

PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.jmps.2019.103780

关键词

Anisotropic material; constitutive behavior; diffusion; variational calculus; thermodynamic extremal principle

资金

  1. Austrian Federal government (Bundesministerium fur Verkehr, Innovation and Technologie)
  2. Austrian Federal government (Bundesministerium fur Wirtschaft and Arbeit)
  3. Styrian Provincial Government [A1.23, A2.32]

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Onsager's Reciprocal Relations between thermodynamic forces and fluxes, for which Onsager was awarded the Nobel Prize, automatically follow from Thermodynamic Extremal Principles. Thus, the Principles are up to now non-applicable for the treatment of experimentally determined or theoretically modeled non-reciprocal systems as e.g. those in the magnetic field. However, we can demonstrate that adding of a certain barrier constraint as bilinear form of thermodynamic forces and fluxes accounted by the Thermodynamic Extremal Principles provides to non-reciprocal relations between the thermodynamic forces and fluxes. Such a novel idea may contribute to a better understanding of physics behind non-reciprocal systems. (C) 2019 Elsevier Ltd. All rights reserved.

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