期刊
JOURNAL OF THE EUROPEAN CERAMIC SOCIETY
卷 40, 期 8, 页码 3249-3261出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.jeurceramsoc.2020.02.029
关键词
Silicon-manganese slag; Transparent glass-ceramics; Mn-doped CaF2 nanocrystals; Colour-controllable change
资金
- National Natural Science Foundation of China [51672025, 51772023, 51572020]
- Major Projects of Science and Technology in Shanxi Province [MC2016-03]
Silicon-manganese slag was firstly used to prepare the transparent colour-controlled glass-ceramics containing Mn-doped CaF2 nanocrystals. The maximum utilization ratio of slag reaches to 27.04 wt%, and the colour of the samples trended red-brown to red light as the added slag content increased. The transparent glass-ceramics could be prepared when crystallized between 650 and 710 degrees C for 2 h, and had a minimum transmittance of 67.95 % at a wavelength of 780 nm. Increasing the content of added slag caused the emission spectrum to shift, demonstrating the ability to control the colour of the transparent glass-ceramics, and also enhanced the fluorescence intensity. The crystallization behaviour conversely has little effect on the colour change, but can increase the fluorescence intensity. In general, this work provides a new approach for the comprehensive utilization of silicon-manganese slag for applications in optical engineering.
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