期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 142, 期 11, 页码 4975-4979出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b13232
关键词
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资金
- National Creative Research Initiative programs of the National Research Foundation of Korea (NRF) - Korean government (MSIP) [2012R1A3A2048814]
- NRF - MSIP [NRF-2017R1A2B2009672]
- Institute for Basic Science in Korea [IBS-R10-A1]
- National Natural Science Foundation of China [21306107]
- Natural Science Foundation of Shandong Province, China [ZR2019MB038]
A novel multifunctional aminophenylboronic acid connected to a diphenylketone gives both circular dichroism and fluorescence signals by in situ generation of a BODIPY-like chromophore in the presence of aminoalcohols. DFT calculations were used to understand the role of each functional group in the mechanism. This new sensor can distinguish different aminoalcohols and quantitatively indicate the concentration of the substrate, allowing for the convenient determination of the ee of racemic mixtures with a single probe.
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