期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 142, 期 7, 页码 3583-3592出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b13303
关键词
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资金
- Natural Sciences and Engineering Research Council of Canada (NSERC)
- National Natural Science Foundation of China Program [51602111]
- Xijiang RD Team
- University of Waterloo
Rational regulation on polysulfide behaviors is of great significance in pursuit of reliable solution-based lithium-sulfur (Li-S) battery chemistry. Herein, we develop a unique polymeric zwitterion (PZI) to establish a smart polysulfide regulation in Li-S batteries. The zwitterionic nature of PZI integrates sulfophilicity and lithiophilicity in the matrix, fostering an ionic environment for selective ion transfer through the chemical interactions with lithium polysulfides (LiPS). When implemented as a functional interlayer in the cell configuration, PZI empowers strong obstruction against polysulfide permeation but simultaneously allows fast Li+ conduction, thus contributing to significant shuttle inhibition as well as the resultant facile and stable sulfur electrochemistry. The PZI-based cells realize excellent cyclability over 1000 cycles with a minimum capacity fading rate of 0.012% per cycle and favorable rate capability up to 5 C. Moreover, a high areal capacity retention of 5.3 mAh cm(-2) after 300 cycles can be also obtained under raised sulfur loading and limited electrolyte, demonstrating great promise in developing high-efficiency and long-lasting Li-S batteries.
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