期刊
JOURNAL OF THE AMERICAN CHEMICAL SOCIETY
卷 142, 期 2, 页码 700-704出版社
AMER CHEMICAL SOC
DOI: 10.1021/jacs.9b12358
关键词
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资金
- National Natural Science Foundation of China [21531006, 21701035, 21773163]
- Priority Academic Program Development of Jiangsu Higher Education Institutions
- Project of Scientific and Technologic Infrastructure of Suzhou [SZS201905]
To obtain a pure product without the isomer byproducts is a goal that many chemists are pursuing. As one kind of very important synthesis method, the photochemical reaction is simple and straightforward yet low-selective. In this work, a coordination interaction based oriented synthesis strategy has been proposed to realize the precise stereochemical control of the isomeric cyclic compounds in the photocycloaddition reaction. Through fixing the reactants via coordination interactions, the arrangements and configurations of the reactants can be adjusted, thereby successfully producing all of the related photocycloaddition products without isomer byproducts for the first time. This work not only provides a new route to synthesize the pure cyclic compounds but also expands the application of the photocycloaddition reaction.
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