期刊
JOURNAL OF SOLID STATE ELECTROCHEMISTRY
卷 24, 期 1, 页码 237-243出版社
SPRINGER
DOI: 10.1007/s10008-019-04456-6
关键词
Copper oxide; Selective sensor; Nanozyme sensor; Microstructures; Nanoparticle assembly
Remarkable selective analysis of biomolecules i.e., glucose and ascorbic acid on copper oxide facets was reported for the first time. The copper oxide nanostructures were synthesized using different Cu-ions sources i.e., CuCl2 and CuSO4 by utilizing the hydrothermal method, which congregates in flower and hollow sphere morphologies, respectively. Interestingly, the results showed a comparable sensitivity and selectivity of CuO nanostructures toward glucose and ascorbic acid. To provide a deep understanding of the key factors that predominate the efficiency and selectivity of nanostructured CuO toward these biomolecules, density functional theory (DFT) calculations were accomplished. Five different crystal facets including (002), (200), (202), (111), and (110) were considered and their binding energies with the biomolecules were investigated. It was found that the facets with rich Cu or O atoms might control the selectivity toward glucose and ascorbic acid. This approach will be helpful for designing sensitive and selective targeted nanomaterial-based sensors.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据