期刊
JOURNAL OF POLYMER RESEARCH
卷 27, 期 4, 页码 -出版社
SPRINGER
DOI: 10.1007/s10965-020-02045-0
关键词
Electrical properties; Thermomechanical; Thermal properties; Phase morphology; Relaxation; Microstructures
Ternary-nanocomposites of polyamide 12 (PA-12) and multi-walled carbon nanotubes-embedded-polypropylene (MWCNT-embedded-PP) were fabricated by direct-melt-mixing-route and characterized for their dispersion-nanomorphology and phase-selective micromorphology. The crystallite sizes remained in the range of 8-9 nm and a broadening in loss-tangent peaks shifting towards higher temperatures with MWCNT was observed. The DC electrical conductivity remained dependent on the change in morphology from domain-dispersed (MWCNT-embedded-PP dispersed in PA-12 matrix) in PA-12/PP-MWCNT (70:30) to quasi-co-continuous (MWCNT-embedded-PP forming elongated domains of PP-MWCNT dispersed in PA-12 matrix tending to be near-continuous) in PA-12/PP-MWCNT (60:40). The conceptual feasibility of designing nanocomposites wherein the switch-over in solid-state relaxation behaviour vis-a-vis electrical conductivity is thus found to be controlled by morphology that ensures phase-selective conductive response for functional applications, as in flexible electronics, unlike the ones with rigid and high melting (thermally stiff) polyamides such as polyamide 6 or polyamide 66.
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