期刊
JOURNAL OF PHYSICAL CHEMISTRY LETTERS
卷 11, 期 2, 页码 567-573出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpclett.9b03539
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- Ministry of Science and Technology Taiwan [MOST 108-2112-M-033-008, 107-2112-M-033-004-MY3]
Visible-transparent luminescent solar concentrators (VT-LSCs) can be integrated with solar cells for designing solar glasses. Recently, rare-earth complexes, semiconductor nanocrystals, and carbon nanodots (CNDs) have been applied in developing VT-LSCs. However, several challenges still existed, such as quantum yields (QYs) at high-loading contents, scattering/reabsorption losses, and stability. Here, highly luminescent and visible-transparent composites based on organosilane-functionalized CNDs (Si-CNDs) cross-linked in the siloxane matrix were prepared. The composites with a high-loading content (similar to 10 wt %) possess ultrahigh QYs of similar to 94% due to surface passivation, cross-linking-enhanced emission, and negligible inter-CND energy transfer. Moreover, they still appear exceptionally transparent and, thus, are suitable for VT-LSCs. Eco-friendly VT-LSCs without colored tinting were fabricated, yielding high internal and external quantum efficiencies of similar to 66% and similar to 3.9%. Our demonstration would pave a bright way for the utilization of eco-friendly VT-LSCs in solar glasses.
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