期刊
JOURNAL OF PHYSICAL CHEMISTRY C
卷 124, 期 1, 页码 83-91出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.jpcc.9b09018
关键词
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资金
- Natural Science Foundation of Shanghai [19NR1413000, 13ZR1411900]
- Shanghai Alliance Plan [LM201881, LM201751]
- Shanghai Leading Academic Discipline Project [B502]
- Shanghai Key Laboratory Project [08DZ2230500]
In this work, novel porous Co9S8 nanosheet arrays are prepared on Co foam through a simple and scalable chemical liquid -phase processing strategy, which involves the uniform growth of cobalt hydroxide hydrogen phosphate microbelts followed by subsequent in situ sulfidation with sodium sulfide at room temperature. As -prepared porous Co9S8 nanosheet arrays can be directly used as binderless electrodes for a supercapacitor. Even at a high mass loading of 11.54 mg cm(-2), it delivers a high capacitance of 14518.9 mF cm -2 (1279.4 F g-') and an exceptional cycle life with a capacitance retention of 85.7% after 15000 cycles at 200 mA cm -2. Moreover, an assembled asymmetric supercapacitor based on an activated carbon negative electrode delivers an encouraging energy density (42.9 W h kg(-1) at 828.5 W kg(-1)) and an excellent cycle life (86% retention after 10000 cycles). This method can be extended to design and construct other high-performance sulfide electrodes for supercapacitors and other energy storage systems.
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