期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 5, 页码 3426-3439出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b03197
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资金
- DST (SERB) [EMR/2016/005885]
- UGC
This report presents the oxygenation of C-H bonds via the merger of photocatalysis and Pd catalysis. Herein, we describe the utilization of a photocatalyst to oxidize an organopalladium(II) intermediate to high-valent Pd-III or Pd-IV intermediates, which promotes the formation of C-O bonds. The demonstrated method works efficiently with various directing groups, such as oxime ether and benzothiazole. The applicability of this direct C-O bond formation method is shown by synthesizing several metal complexes of 2-(benzo[d]thiazol-2-yl)phenol that can be used in organic light-emitting diodes and pharmaceuticals.
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