期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 5, 页码 3000-3009出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b02807
关键词
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资金
- DST -SERB (Early Career Research Award)
- DST INSPIRE Faculty Scheme
- DST -FIST program (Department of Chemistry, NIT-Trichy)
- DST, GOI
Herein, we have reported a metal-free, mild, and novel protocol for the synthesis of various triarylmethanes (TRAMs) in moderate to good yields via the reactions of aryl boronic acids and ortho-hydroxyarylaldehydes in the presence of stoichiometric amounts of Et3N in dichloroethane at 80 degrees C. Additionally, the synthetic utilities of few synthesized TRAMs were proven by carrying out bromination on the -OH-containing aryl part and followed by functionalization of bromine through a palladium-catalyzed Suzuki-Miyaura cross-coupling reaction with arylboronic acids in good yields. The -OH group was also alkylated and arylated through simple alkylation and Chan-Lam reaction, respectively.
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