期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 6, 页码 4354-4364出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.0c00048
关键词
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资金
- Natural Science Foundation of China [21402068, 21502075, 21762018]
- Natural Science Foundation of Jiangxi Province [20192BCBL23009]
- Open Project Program of Key Laboratory of Functional Small Organic Molecule, Ministry of Education, Jiangxi Normal University [KLFS-KF-201406]
An efficient approach to prepare trifluoromethyl-alpha-carbolines and ester group-substituted alpha-carbolines via the tandem cyclization reaction of 2-(2-aminophenyl)acetonitriles and trifluoromethyl 1,3-diones or beta,gamma-unsaturated alpha-ketoesters was reported. The transformation proceeded smoothly in the presence of catalytic environmental-benign iron salts, which are used to prepare the desired products in moderate to good yields.
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