期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 4, 页码 2242-2249出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b02957
关键词
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资金
- National Natural Science Foundation of China [21272115]
- Natural Science Foundation of Jiangsu Province [BK20161494]
- State Key Laboratory of Fine Chemicals [KF1704]
An anionic iridium complex [Cp*Ir(2,2'-bpyO)(OH)][Na] was found to be a general and highly efficient catalyst for transfer hydrogenation of ketones and imines with methanol under base-free conditions. Readily reducible or labile substituents, such as nitro, cyano, and ester groups, were tolerated under present reaction conditions. Notably, this study exhibits the unique potential of anionic metal-ligand bifunctional iridium catalysts for transfer hydrogenation with methanol as a hydrogen source.
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