期刊
JOURNAL OF ORGANIC CHEMISTRY
卷 85, 期 2, 页码 798-805出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.joc.9b02811
关键词
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资金
- JSPS KAKENHI [18K0S123]
- Naito Foundation
A formal total synthesis of manzacidin B is described. beta,beta-Disubstituted gamma-hydroxy-beta-aminoalcohol, the key structure of manzacidin B, is stereoselectively constructed via sequential Henry reactions. By taking advantage of noncovalent interactions, such as intramolecular hydrogen bonding and chelation, we could diastereodivergently control the stereoselectivity of the Henry reaction.
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