期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 382, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jhazmat.2019.120970
关键词
Fe-V-Ti catalysts; NH3-SCR; SO2 resistance; Reaction mechanism
资金
- National Natural Science Foundation of China [51822811, 21637005,21607149]
- National Key R&D Program of China [2016YFCO205301, 2017YFCO212502]
A series of Fe-V-Ti oxide catalysts were prepared by a co-precipitation method, among which the Fe0.1V0.1TiOx catalyst showed the optimal NH3-SCR performance and excellent SO2 resistance. Fe0.1V0.1TiOx achieved > 90% NOx conversion at 225-450 degrees C under a GHSV of 200,000 h(-1). When introducing SO2 and H2O to the SCR reaction for 24 h, the NOx conversion maintained a level above 93% at 250 degrees C. The Raman and Mossbauer spectra showed that FeVO4 and Fe2O3 coexisted on the surface of TiO2. In Fe-V-Ti catalysts, the charge interaction between Fe2O3 and FeVO4 as well as the electronic inductive effect between Fe and V species resulted in the improvement of SCR activity and N-2 selectivity at high temperatures. The NH3-SCR process on the Fe0.1V0.1TiOx catalyst mainly followed the Eley-Rideal (E-R) reaction mechanism with gaseous NO reacting with adsorbed NH3 adsorbed species.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据