Distorted polymeric carbon nitride via carriers transfer bridges with superior photocatalytic activity for organic pollutants oxidation and hydrogen production under visible light

Polymeric carbon nitride (PCN) has become the most promising metal-free photocatalysts but its activity is low. Molecule doping of PCN has been proved to be an effective strategy to achieve high photocatalytic performance. Herein, we report a bottom-up method to synthesize modified PCN, which includes 2,5-dibromopyrazine doping, thermal-induced exfoliation and condensation/polymerization. The incorporation of electron-deficiency 2,5-dibromopyrazine into the PCN framework can effectively tune the electronic structures and improve the charge-carrier separation. In addition, the incorporation of 2,5-dibromopyrazine induced significant structural changes from planar symmetric to distortion. The optimized pyrazine doped PCN showed a reaction rate enhancement of 4-fold for the degradation of sulfamethazine compared to that of conventional urea-based PCN. Further reactive species and degradation intermediate detection studies, indicated that O-center dot(2)- was generated during the photocatalytic process, which could lead to the decomposition, and finally mineralization of sulfamethazine. 2,5-Dibromopyrazine doped PCN also leads to a 6.3-fold improvement in H-2 generation with the visible light. Especially, phytotoxicity experiments showed that the toxicity of sulfamethazine after degradation is greatly reduced, and the as-prepared photocatalyst is environmentally friendly.