期刊
JOURNAL OF HAZARDOUS MATERIALS
卷 384, 期 -, 页码 -出版社
ELSEVIER
DOI: 10.1016/j.jhazmat.2019.121487
关键词
Dielectric constant; Lithium-ion battery cathode; Recycling process; Microwave heating; Reduction roasting
资金
- National Natural Science Foundation of China [51564033, 51961020]
- Analytical Testing Center of Kunming University of Science and Technology
As a hazardous material to the environment and human health, spent lithium-ion batteries need to be recycled in a reasonable way. To explore the effect of microwave heating on spent lithium-ion batteries (LIBs) recycling, the microwave-absorbing properties of a spent cathode powder (LiNixCoyMnzO2) were studied by measuring its dielectric properties from 25-900 degrees C at 2450 MHz under different conditions (temperature, carbon dose and apparent density). X-ray diffraction and thermogravimetric analysis (TGA) were used to study decomposition and reduction reactions in the heating process. The results indicated that the cathode material has good microwave-absorbing properties over the entire temperature range (25-900 degrees C), especially when mixed with carbon. As the reduction reactions proceed, the dielectric properties of the material increase rapidly from 600 degrees C, which means that microwave heating can promote a carbothermal reduction reaction. The effect of the carbon dose on the dielectric properties indicates that the carbothermal reduction reaction can fully occur when the carbon dose reaches 18%. Furthermore, the best microwave-absorbing performance can be achieved when the apparent density of the material is 1.41 g/cm(3). These studies have established a basis for research towards the direct recovery of lithium from LIBs by microwave reduction roasting.
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