期刊
JOURNAL OF COLLOID AND INTERFACE SCIENCE
卷 557, 期 -, 页码 367-380出版社
ACADEMIC PRESS INC ELSEVIER SCIENCE
DOI: 10.1016/j.jcis.2019.09.036
关键词
Supercapacitors; Rate capability; Relaxation time constants; Capacitance
The low energy densities of supercapacitors limit their utilization as energy storage and energy conversion devices. To overcome this limitation, here we present a ternary nanocomposite of reduced graphene oxide (rGO)/nickel hydroxide (Ni(OH)(2)/polyaniline (PANI), with methane sulfonic acid as dopant, having weight percentages of 14%:14%:72% (G14NP), respectively, as an electrode material for supercapacitor. With 1 M sulfuric acid (H2SO4) as the electrolyte, the supercapacitor yields a high energy density of 120.48 W h kg(-1), comparable with those of Li-ion batteries. The G14NP also exhibits good electrochemical performance with a specific capacitance of 602.40 F g(-1) and a power density of 2584.83 W kg(-1), at a current density of 1 A The G14NP also exhibits a promising stability of its electrochemical performances even after 16,500 cycles at a potential scan of 400 mV s(-1). Remarkably, the composite performs exceptionally well at a potential window available in an aqueous electrolyte. The sustainability to high current loading while charging and its power backup application is satisfactorily demonstrated, by charging with a commercial 9 V battery. (C) 2019 Elsevier Inc. All rights reserved.
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