Influence of rectilinear vs radial advection on the yield of A plus B → C reaction fronts: A comparison

In the presence of advection at a constant flow rate in a rectilinear geometry, the properties of planar A + B -> C reaction fronts feature the same temporal scalings as in the pure reaction-diffusion case. In a radial injection geometry where A is injected into B radially at a constant flow rate Q, temporal scalings are conserved, but the related coefficients depend on the injection flow rate Q and on the ratio. of initial concentrations of the reactants. We show here that this dependence of the front properties on the radial velocity allows us to tune the amount of product obtained in the course of time by varying the flow rate. We compare theoretically the efficiency of the rectilinear and radial geometries by computing the amount of product C generated in the course of time or per volume of reactant injected. We show that a curve gamma(c)(Q) can be defined in the parameter space (gamma, Q) below which, for similar experimental conditions, the total amount of C is larger in the radial case. In addition, another curve gamma*(Q)