期刊
INTERNATIONAL JOURNAL OF ELECTROCHEMICAL SCIENCE
卷 15, 期 3, 页码 1982-1995出版社
ESG
DOI: 10.20964/2020.03.18
关键词
Bio-waste derived; Activated carbon; Nitrogen-doped; Electrochemical capacitors
资金
- National Natural Science Foundation of China [21471135, 21506198]
- Key R&D and Promotion Projects in Henan Province [2019410104000024]
- Doctoral foundation of Zhengzhou University of Light Industry [2017BSJJ043]
In this study, longan shell as biowaste material has been collected to prepare activated carbon for supercapacitors. The biochar was firstly carbonized and then etched by KOH to transform into porous carbon architecture. With the help of XRD, SEM, Raman and XPS, physical and chemical properties of the samples were investigated and the optimized parameters of preparation is the etching ratio of 1:2 at pre-carbonization temperature of 500 degrees C following the etching temperature at 700 degrees C. Due to the nitrogen-doping carbon combined with oxygen-rich functional groups as well in-situ CaCO3 template, the achieved activated carbon possesses a specific capacitance of 210 F g(-1) at a current density of 0.5 A g(-1), with a moderate rate capability at 20 A g(-1). Symmetrical supercapacitor has also been assembled and its power density reaches 17.2 Wh kg(-1) at energy density of 1, 000 W kg(-1) with a high capacitance retention of 68.3% from 1 A g(-1) to 40 A g(-1). After tested at 4 A g(-1) for 10,000 cycles, the capacitor only shows slightly capacitance decay with the retention almost 100%, demonstrating a practical application value in supercapacitors.
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