期刊
INTERNATIONAL JOURNAL OF APPLIED CERAMIC TECHNOLOGY
卷 17, 期 4, 页码 1918-1929出版社
WILEY
DOI: 10.1111/ijac.13496
关键词
characterization; co-precipitation; doping; photocatalytic-activity
In this study, an effective photodegrading properties of WO3 nanoparticles has been enhanced by doping with cerium. To achieve our goal pristine and Ce-doped WO3 nanoparticles were prepared by a simple and cost effective co-precipitation route. Characterization of all the specimens were conducted which showed that there were no noticeable structural changes. WO3 retained its monoclinic structure even after doping with (3%, 5%, 8%, 10%) cerium which was also confirmed with X-ray diffraction (XRD) and Raman spectroscopy. In addition, XRD and Fourier transform infra-red spectroscopy also confirm that no new phases were formed in doped specimens. XRD also depicts that minimum crystallite size is achieved at 3% cerium doping. Scanning electron microscope images show decrease in particle size initially at 3% cerium doping, that is, 80 +/- 2.5 nm. In contrast, further increase in doping percentage increases crystallite and particle sizes. Additionally, defect generation increased at lower doping percentage 3%. In contrast, further increase in dopant (5%, 8%, 10%) caused defect annihilation process to dominate over defect generation. C/C-o ratio and rate constant (K-MB) values suggest that maximum degradation of methylene blue will occur at 3% cerium doping due to increase in crystalline defects. Ultraviolet visible Spectroscopy further validates C/C-o ratio and degradation rate constant values by showing drastic decline in peak intensity at 3% cerium doping. Therefore, 3% cerium-doped WO3 is more effective photocatalyst to degrade methylene blue in comparison to most of the previously used photocatalysts. The prepared cerium-doped WO3 nanoparticles as a sun light driven photocatalyst, may be utilized for industrial wastewater purification.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据