期刊
INTERNATIONAL JOURNAL OF ADHESION AND ADHESIVES
卷 95, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.ijadhadh.2019.102404
关键词
Polyurethane; Cellulose acetate and castor oil-based adhesives; Rheology; Mechanical properties of adhesives; Viscoelasticity
资金
- MINECO-FEDER [CTQ2014-56038-C3-1R]
- Junta de Andalucia [TEP-1499]
- Ministerio de Educacion [FPU13/01114]
In this study, cellulose acetate and castor oil have been used to synthesize new eco-friendly alternatives to traditional polyurethane adhesives. First, cellulose acetate (CA) was modified with diphenylmethane-4,4'-diisocyanate (MDI) at different NCO:OH molar ratios, ranging from 2 to 4.53, and then the resulting biopolymers were mixed with castor oil (CO) at 1:1 wt ratio. The fully cured bio-sourced adhesives were theologically characterized by applying dynamic oscillatory torsional tests at different temperatures (from -30 up to 200 degrees C). Furthermore, their adhesion performance on stainless steel and poplar wood substrates was analyzed, by conducting standardized mechanical tests, namely single-lap shear and 180 degrees peel strengths, at room temperature and 100 degrees C. Fourier transform infrared spectroscopy-attenuated total reflectance along with differential scanning calorimetry and thermogravimetric analysis were also performed. Above a critical NCO:OH ratio, a thermotheological simplicity was found within the whole temperature range considered, being able to apply the t-T superposition principle. However, an increase in the temperature led to a depletion in their mechanical performance, thus reducing their temperature range of application. Thermal and spectroscopic analysis corroborated the complete disappearance of free isocyanate during the first few days of curing, and a segmented structure, typical of polyurethanes. Optimum thermo-rheological behaviour and adhesion performance on wood and stainless steel of the bio-sourced polyurethanes studied were found for NCO:OH molar ratios higher than 3.5, which was related to the higher compatibility between hard and soft microdomains.
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