期刊
INORGANIC CHEMISTRY
卷 59, 期 5, 页码 2853-2860出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b03176
关键词
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资金
- NSFC [21601145, 21871220]
- Northwest AF University [2452019002]
Based on the mixed carboxylate ligands synthesis strategy, an indium-organic framework, (Me2NH2)(1.5)[In-1.5(FBDC)(BDC)]center dot 2.5NMF center dot CH3CN (1) has been constructed by using the mixed (2,5-di(2',5'-dicarboxylphenyl)-difluorobenzene (H4FBDC) and terephthalic acid (H2BDC). Compound 1 contains a 3D intersecting pore system which surface is modified by F atoms, and it has excellent stability in pH = 2-12 aqueous solutions. The activated 1 shows high separation for C2H2/CO2 and C2H2/CH4. Moreover, 1 not only has strong luminescence but also has the high selectivity and sensibility of fluorescence detection to nitrofurazone (NZF) in antibiotic sensing experiments, which can be used as a luminescence sensor for NZF detection.
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