期刊
INORGANIC CHEMISTRY
卷 59, 期 5, 页码 2733-2746出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b03093
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资金
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft (DFG) [KR4782/3-1]
- University of Regensburg
- Friedrich Schiller University Jena
The synthesis of 3,4-ethylene-bridged 1,1,2,5-tetrasubstituted biguanides is reported, which are accessible by three alternative routes. Exemplary molecular structures of the ligand and an observed side product have been elucidated by X-ray diffraction analysis. Mono- and dinuclear complexes of the biguanide in both its neutral and monoanionic forms were obtained, including examples of aluminum, copper, magnesium, potassium, tin, and zinc, indicating a versatile coordination behavior, as evidenced by means of single-crystal X-ray diffraction analysis.
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