期刊
INORGANIC CHEMISTRY
卷 59, 期 1, 页码 687-694出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b02948
关键词
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资金
- National Key Research and Development Program of China [2018YFA0306001]
- NSFC [21822508, 21620102002, 21701198, 21821003]
- Pearl River Talent Plan of Guangdong [2017BT01C161]
The combination of magnetic interaction with high magnetic anisotropy provides a promising way for modulating/fine-tuning molecular magnetic behaviors. Here, we show the building block approach for the synthesis of a family of dilanthanide single-molecule magnets (SMMs) bridged with a cyanometallate starting from a monolanthanide SMM. Contingent on the central para-/diamagnetic [M(CN)(6)](3-) (M = Fe, Co) integrated between two highly anisotropic pentagonal-bipyramid Dy(III) subunits, the remanence of magnetization is OFF/ON below 15 K and they respectively display a record reversal barrier of 659 K among d-f SMMs and 975 K among cyanobridged SMMs.
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