期刊
INORGANIC CHEMISTRY
卷 59, 期 6, 页码 3367-3376出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.inorgchem.9b03189
关键词
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资金
- Fonds der Chemischen Industrie
- Deutsche Forschungsgemeinschaft
Bismepines are 3-fold unsaturated sevenmembered rings containing one bismuth atom. A set of dibenzobismepine complexes have been synthesized and isolated, among them a dinuclear bismepine, halobismepines, and cationic bismepines. They were investigated with respect to the structural properties, olefin-bismuth interactions, heteroaromaticity, and Lewis acidity (including a comparison with a range of simple bismuth and group 13 Lewis acids). Applied analytical techniques include NMR spectroscopy, single-crystal X-ray analysis, elemental analysis, and density functional theory calculations.
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