期刊
EUROPEAN JOURNAL OF ORGANIC CHEMISTRY
卷 2020, 期 6, 页码 702-707出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/ejoc.201901779
关键词
Boron; Methoxynitroarenes; Alcohols; Ether interchange reaction; Alkyl nitroaromatic ethers
资金
- National Natural Science Foundation of China [21172200, 21702191]
The first protocol for boron-promoted ether interchange reaction of methoxynitroarenes was described. A series of methoxynitroarenes and alcohols, including primary, secondary, as well as tertiary alcohols were reacted smoothly in moderate to good yields under the optimized reaction conditions. This protocol constitutes an operationally simple and scalable strategy for the synthesis of alkyl nitroaromatic ethers. Moreover, the new reactivity of boron reagents was discovered.
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