Intensification of the ultrafiltration of real oil-contaminated (produced) water with pre-ozonation and/or with TiO2, TiO2/CNT nanomaterial-coated membrane surfaces

In the present study, commercial PES, PVDF, PTFE ultrafilter membranes, and two different nanomaterial (TiO2 and TiO2/CNT composite)-covered PVDF ultrafilter membranes (MWCO = 100 kDa) were used for the purification of an industrial oil-contaminated (produced) wastewater, with and without ozone pretreatment to compare the achievable fouling mitigations by the mentioned surface modifications and/or pre-ozonation. Fluxes, filtration resistances, foulings, and purification efficiencies were compared in detail. Pre-ozonation was able to reduce the total filtration resistance in all cases (up to 50%), independently from the membrane material. During the application of nanomaterial-modified membranes were by far the lowest filtration resistances measured, and in these cases, pre-ozonation resulted in a slight further reduction (11-13%) of the total filtration resistance. The oil removal efficiency was 83-91% in the case of commercial membranes and > 98% in the case of modified membranes. Moreover, the highest fluxes (301-362 L m(-2) h(-1)) were also measured in the case of modified membranes. Overall, the utilization of nanomaterial-modified membranes was more beneficial than pre-ozonation, but with the combination of these methods, slightly higher fluxes, lower filtration resistances, and better antifouling properties were achieved; however, pre-ozonation slightly decreased the oil removal efficiency.