Pollution evaluation and health risk assessment of airborne toxic metals in both indoors and outdoors of the Pearl River Delta, China

Background: Industries deveploped cities in the Pearl River Delta (PRD) are suffering serious atmospheric metals pollution, in which, people's health risks after inhaling particulate matter (PM) with airborne toxic metals might be rising. This study provides the latest and comprehensive pollution profiles of toxic metals both from indoors and outdoors in PRD. Method: Total 22 pairs of indoor and outdoor total suspended particulates (TSP), PM10 and PM2.5 samples in residential area were synchronously sampled and investigated in detail within 9 main cities of the PRD, China. The concentrations of the Zn, Pb, Mn, Ni, As, V, Sb and Cd in the samples were measured by inductively coupled plasma mass spectrometry (ICP-MS). Health risk assessment via inhalation of residents was estimated by EPA recommended model with exposure parameters of Chinese population indoor and outdoor activity pattern. Results: The trends followed as Zn > Pb approximate to Mn > Ni > As > V > Sb approximate to Cd for both indoors and outdoors. Investigated metals were found to be dominantly distributed in PM2.5 for both indoors and outdoors. The concentrations of outdoor PM and the most of metals were significantly higher than those of indoors. The results concluded that toxic metals might be from regional emission, such as Pb from ceramic factory, Ni from motor factory and V from oil combustion of ship. In health risk assessments, LCR is higher than 1.00E-06 for adults, while contrary to children in the PRD. Among four carcinogenic metals, LCR of As and Cd are higher than 1.00E-06 in some cities. In addition, HI below one for both adults and children in the PRD. Conclusions: Outdoor metals concentrations are related to local industry types, while indoor metals are mainly from outdoor. Health risk assessments indicated that adults suffered unsafe cancer risk from metals, especially As and Cd in some cities, while both adults and children did not suffer non-carcinogenic risks.