期刊
ENERGY
卷 195, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.energy.2020.117010
关键词
Pyrolysis; Kinetics; Biomass; Hemicellulose; Cellulose
资金
- National Natural Science Foundation of China [51806202, 51806106]
- Natural Science Foundation of Hubei Province of China [2018CFB352]
- Research Fund of Key Laboratory of Mining Disaster Prevention and Control [MDPC201921]
- Fundamental Research Funds for the Central Universities, China University of Geosciences (Wuhan) [CUG170672]
Thermal interactions of isolated hemicellulose and cellulose were analyzed during biomass pyrolysis. Different from the previous researches focus on pyrolysis products, the current study paid attention to the kinetic parameters coupled with artificial intelligence optimization algorithm to explore whether the interactions of hemicellulose and cellulose could be ignored or not. A series of thermogravimetric experiments were conducted based on isolated hemicellulose, cellulose and their mixture at various heating rates. The experimental results showed that the peak locations of mixture pyrolysis exactly corresponded to the peak locations of isolated hemicellulose and cellulose. Furthermore, the kinetic parameters obtained from isolated hemicellulose and cellulose were applied to predict the pyrolysis behaviors of mixture, and the predicted results agreed well with experimental data. Eventually, it was speculated that the thermal interactions of isolated hemicellulose and cellulose could be ignored during the whole pyrolysis process from the point of kinetic parameters. Meanwhile, the pyrolysis behaviors of real biomass were compared with that of isolated hemicellulose and cellulose. Moreover, the effects of kinetic parameters on the thermogravimetric results were studied based on the global sensitivity analysis, indicating the activation energy and pre-exponential factor playing the most important role on the pyrolysis process of mixture. (C) 2020 Elsevier Ltd. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据