期刊
ELECTROCHIMICA ACTA
卷 334, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2019.135563
关键词
Carbon dioxide; Electrochemical reduction; Formate; Nanostructured bismuth
资金
- National Natural Science Foundation of China [21975229]
- Natural Science Foundation of Zhejiang Province [LY19E020001, LY19B060003]
- Joint Open Fund of Jiangsu Collaborative Innovation Center for Ecological Building Material and Environmental Protection Equipments and Key Laboratory for Advanced Technology in Environmental Protection of Jiangsu Province
Electrochemical reduction of CO2 (ECR) into formate is an efficient and environmentally friendly approach contributing to carbon-neutral cycle. However, conventional catalysts for ECR usually suffer from low product selectivity, inferior activity and poor durability. Herein, we highlight Bi nanoparticles embedded in nitrogen doped porous carbon (Bi@NPC) as a promising integrated catalyst for ECR. This catalyst demonstrates a remarkable formate faradaic efficiency of 92.0%, and more encouragingly, a high formate current density of 14.4 mA cm(-2) at a low potential of -1.5 V (vs SCE) in 0.1 M KHCO3 solution, which is significantly superior to the individual Bi nanoparticles (Bi-NP). Besides, the Bi@NPC catalyst exhibits a robust durability for 20 h operation. The advanced electrocatalytic performance of the Bi@NPC catalyst is likely attributed to the ensemble effect of Bi nanoparticles and NPC matrix. This attractive route discloses a broad prospect for the development of a promising integrated catalyst for ECR. (C) 2019 Elsevier Ltd. All rights reserved.
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