期刊
ELECTROCHIMICA ACTA
卷 330, 期 -, 页码 -出版社
PERGAMON-ELSEVIER SCIENCE LTD
DOI: 10.1016/j.electacta.2019.135312
关键词
ZnO@SnO2; Heterojunction; Lithium storage property; Lithium-ion batteries
资金
- National Natural Science Foundation of China [61701402, 51872226]
- General Program for International Science and Technology Cooperation Projects of Shaanxi Province [2019KW-029]
ZnO@SnO2 heterojunction hybrid with a novel test-tube brush-like structure is fabricated successfully through a facile hydrothermal approach. Sixfold symmetric epitaxial growth of SnO2 nanowires on non-polarized planes of ZnO microrods is realized via the approach. The synthesized ZnO@SnO2 with the unique structure as a lithium-ion battery anode material exhibits enhanced electrochemical properties when compared with the single-phase ZnO microrod and SnO2 nanowire electrode. The existence of heterostructure on the influence of lithium storage performance is studied by using first-principles calculations through density functional theory method. Experimental and theoretical calculation results demonstrate that the excellent electrochemical performance of the heterojunction hybrid is ascribed to the synergistic effect of the respective components. The construction of ZnO@SnO2 heterojunctions can not only provide facile Li+ kinetics and enhanced ion diffusion, but also improve the mobility rate of electrons and holes by means of the presence of internal electric field. (C) 2019 Elsevier Ltd. All rights reserved.
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