期刊
ELECTROCHEMISTRY COMMUNICATIONS
卷 110, 期 -, 页码 -出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.elecom.2019.106642
关键词
Stainless steel; Gradient structure; Passive film; Corrosion resistance
资金
- Beijing Municipal Science and Technology Commission [Z181100005218005]
A 316LN stainless steel with a gradient-nanostructured surface layer was fabricated by rotationally accelerated shot peening (RASP). The thickness of this gradient layer was about 210 mu m. Layer-by-layer electrochemical experiments confirmed that the layer of the gradient steel with the best corrosion resistance is found at a distance of 110 mu m from the surface. The nanostructures and pits generated by RASP produced two opposing effects on its corrosion resistance: the nanocrystals and nano-twins facilitate the formation of a thick, compact passive film which resists corrosion, whereas the pits tend to destroy it. The passive films formed on the pits and on the smoothly nanostructured areas were 5.5 nm and 13.9 nm thick, respectively.
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