期刊
DYES AND PIGMENTS
卷 171, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.dyepig.2019.107775
关键词
Thermally activated delayed fluorescence (TADF); Pyridinecarbonitrile derivatives; Organic light-emitting diodes (OLEDs); Ortho-substitution
资金
- National Research Foundation of Korea (NRF) - Ministry of Science & ICT & Future Planning [2018R1C1B5044977]
- Korea Institute of Energy Technology Evaluation and Planning (KETEP)
- Ministry of Trade & Industry & Energy (MOTIE) of the Republic of Korea [20194030202320]
- Japan Science and Technology Agency (JST), ERATO
- Adachi Molecular Exciton Engineering Project, under JST ERATO, Japan [JPMJER1305]
- International Institute for Carbon Neutral Energy Research (WPI-I2CNER) - Ministry of Education, Culture, Sports, Science & Technology (MEXT)
- National Research Foundation of Korea [2018R1C1B5044977] Funding Source: Korea Institute of Science & Technology Information (KISTI), National Science & Technology Information Service (NTIS)
In this work, we designed and investigated two TADF molecules, AcCN and PxCN, introducing donor moieties into the 3,5-position of 4-pyridinecarbonitrile acceptor core. These D-A-D type compounds exhibit effective utilization of triplet excitons through a reverse intersystem crossing (RISC) process with relatively small singlet-triplet energy splitting (Delta E-ST) values less than 0.1 eV. With their high PL quantum yield (Phi(PL)) and sufficient rate constant for RISC process (k(RISC)), organic light emitting diodes (OLEDs) employing AcCN and PxCN as emitters achieve a maximum external quantum efficiency (eta(ext)) of 20.6% and 15.5%, respectively, with green emissions.
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