期刊
COORDINATION CHEMISTRY REVIEWS
卷 407, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.ccr.2019.213118
关键词
Terminal imido complex; Early transition metals; Group 4-6 metals; Cycloaddition; Nitrogen-containing organic compound
资金
- JSPS
- JSPS KAKENHI Grant [15H05808, 15K21707, 2702]
- National Institutes of Health [1R35GM119457]
- Alfred P. Sloan Foundation
- International Joint Research Promotion Program (Osaka University)
- Multidisciplinary Research Laboratory System (Graduate School of Engineering Science, Osaka University)
- Grants-in-Aid for Scientific Research [15H05808, 15K21707] Funding Source: KAKEN
Imido complexes of early transition metals are key intermediates in the synthesis of many nitrogen-containing organic compounds. The metal-nitrogen double bond of the imido moiety undergoes [2+2] cycloaddition reactions with various unsaturated organic molecules to form new nitrogen-carbon and nitrogen-heteroatom bonds. This review article focuses on reactivity of the terminal imido complexes of Group 4-6 metals, summarizing their stoichiometric reactions and catalytic applications for a variety of reactions including alkyne hydroamination, alkyne carboamination, pyrrole formation, imine metathesis, and condensation reactions of carbonyl compounds with isocyanates. (C) 2019 Elsevier B.V. All rights reserved.
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