期刊
COMPOSITES PART B-ENGINEERING
卷 182, 期 -, 页码 -出版社
ELSEVIER SCI LTD
DOI: 10.1016/j.compositesb.2019.107615
关键词
Graphene networks; Polyurethane foams; Flame carbonization; EMI shielding
资金
- Key Scientific and Technological Project of Henan Province [182102210412]
- National Project Cultivation Foundation of Huanghuai University [XKPY-2019008]
- S&T Innovation 2025 Major Special Programme of Ningbo [2018B10054]
- Natural Science Foundation of Ningbo [2018A610004]
Graphene networks (GNs) with ultralow density of 5.6-8.6 mg/cm(3) were prepared with polyurethane/graphene (PUG) composite foams as templates and ethanol flame as a mild carbonizing condition. After the pyrolysis of the PU matrix in dozens of seconds, the structural integrity of the foams was well preserved by the embedded graphene sheets at a sufficient content (>= 12 wt%), forming interconnected GNs with pore size in nano- and micron-scale. When encapsulated with epoxy resin, the CNs composites showed excellent electrical conductivity of 340-830 S/m at the filler content of 2.5-4.2 wt% and exceptional electromagnetic interference (EMI) shielding effectiveness (SE) of 30-61 dB in sample thickness of 0.9-1.5 mm. The excellent EMI shielding property of GN composites, as well as the mild, high-efficient flame-carbonizing process, make our self-templating method very promising in the facile fabrication of high-performance EMI shielding materials.
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