期刊
CHINESE JOURNAL OF CHEMISTRY
卷 38, 期 5, 页码 453-457出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cjoc.201900431
关键词
Fructose; 1,2-Propylene glycol; Bimetallic catalyst; Hydrogenation
资金
- National Key R&D Program of China [2018YFB1501600]
- National Natural Science Foundation of China [21572212, 51821006, 51961135104]
- Major Science and Technology Projects of Anhui Province [18030701157]
- Strategic Priority Research Program of the CAS [XDA21060101]
- Local Innovative and Research Teams Project of Guangdong Pearl River Talents Program [2017BT01N092]
.Summary of main observation and conclusion The conversion of fructose to 1,2-propylene glycol (PG) is an important process from cellulosic biomass to high-value added chemicals. Herein, Ru-WOx/hydroxyapatite (HAP) catalyst was employed for this reaction and reached up to 91.3% yield of PG at 180 degrees C, 1 MPa initial hydrogen for 8 h in water. On this catalyst, Ru and WOx were highly dispersed on HAP support and they interacted with each other to form a special catalytic center. The lack of isolated Ru or RuW alloy site led to a moderate activity for hydrogenolysis and hindered the further conversion of PG to propanol. The weak basic HAP support efficiently prevented the humin formation. This precisely controlled catalyst has potential in green PG production.
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