期刊
CHINESE CHEMICAL LETTERS
卷 31, 期 9, 页码 2189-2201出版社
ELSEVIER SCIENCE INC
DOI: 10.1016/j.cclet.2019.12.009
关键词
Metal-organic frameworks; Membranes; Nanosheets; Derivatives; Synthesis; Electrocatalysis
资金
- National Natural Science Foundation of China [21805103, 21805104, 21802048]
- Fundamental Research Funds for the Central Universities [2018KFYYXJJ121, 2019KFYXJJS073]
- National 1000 Young Talents Program of China
Metal-organic frameworks (MOFs), as an emerging family of porous inorganic-organic crystal materials, exhibit widely applications in gas storage and separation, drug release, sensing, and catalysis, owing to easily adjustable pore sizes, uniformly distributed metal centers, high surface areas, and tunable functionalities. However, MOF crystal powders are usually difficult to be directly applied into specific devices because of their brittleness, insolubility and low compatibility. Therefore, to expand versatile MOF membranes with robustness and operational flexibility is urgent to satisfy practical applications. Although numerous reports have reviewed the synthesis and applications of MOF membranes, relatively few reports the electrocatalytic properties based on MOF membranes. Herein, this mini-review provides an overview of preparation of MOF membranes, including directed synthesis, secondary growth and electrochemical deposition method. Meanwhile, fabrication of ultrathin 2D MOF nanosheets those can be also defined as a kind of nanoscale MOF membranes is also mentioned. Electrocatalytic performance of oxygen reduction reaction (ORR), oxygen evolution reaction (OER), hydrogen evolution reaction (HER) and CO2 reduction reaction (CO2RR) for diverse MOF membranes/nanosheets and their derivatives are introduced. (C) 2020 Chinese Chemical Society and Institute of Materia Medica, Chinese Academy of Medical Sciences. Published by Elsevier B.V. All rights reserved.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据