期刊
CHEMPHYSCHEM
卷 21, 期 2, 页码 154-163出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/cphc.201900961
关键词
cocrystal; crystal engineering; halogen bonding; hydrogen bonding; photodimerization
资金
- National Science Foundation [LRM DMR-1708673]
A series of cocrystals involving the hydrogen- and halogen-bond donor coformers catechol (cat) and 1,2-diiodotetrafluorobenzene (1,2-di-I-tFb), respectively, is reported. Each coformer forms a cocrystal with each of the three symmetric bipyridines trans-1,2-bis(n-pyridyl)ethylene (n,n '-bpe, where: n=n '=2, 3, 4). Four novel cocrystals (cat) . (3,3 '-bpe), 2(1,2-di-I-tFb) . (2,2 '-bpe), 2(1,2-di-I-tFb) . (3,3 '-bpe), and (1,2-di-I-tFb) . (4,4 '-bpe) comprise components that assemble by either O-H...N hydrogen bonds (cat) or N...I halogen bonds (1,2-di-I-tFb). In (cat) . (3,3 '-bpe), cat acts as a template to support an intermolecular [2+2] photocycloaddition of 3,3 '-bpe. The reactivity occurs via a one-dimensional (1D) hydrogen-bonded tape with stacked and criss-crossed olefins that react stereoselectively and quantitatively to form rctt-tetrakis(3-pyridyl)cyclobutane (3,3 '-tpcb). The reactivity of the criss-crossed olefins is facilitated by a hitherto not reported cis-gauche conformation adopted by cat. The stereochemistry of 3,3 '-tpcb is confirmed in the cocrystal 2(cat) . (3,3 '-tpcb).
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据