期刊
CHEMISTRY-AN ASIAN JOURNAL
卷 15, 期 8, 页码 1272-1276出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/asia.201901714
关键词
Ammonia; Electrocatalysis; Metal-organic frameworks; HKUST-1; N-2 to NH3
资金
- National Natural Science Foundation of China [20974042, 21645008, 21305042]
- Scientific Research Fund of Hunan Provincial Education Department [18A010]
- Science and Technology Department of Hunan Province [14JJ4030]
Electrolytic ammonia synthesis from nitrogen at ambient conditions is appearing as a promising alternative to the Haber-Bosch process which is consuming high energy and emitting CO2. Here, a typical MOF material, HKUST-1 (Cu-BTC, BTC=benzene-1,3,5-tricarboxylate), was selected as an electrocatalyst for the reaction of converting N-2 to NH3 under ambient conditions. At -0.75 V vs. reversible hydrogen electrode, it achieves excellent catalytic performance in the electrochemical synthesis of ammonia with high NH3 yield (46.63 mu g h(-1) mg(-1) (cat.) or 4.66 mu g h(-1) cm(-2)) and good Faraday efficiency (2.45%). It is indicated that the good performance of the HKUST-1 catalyst may originate from the formation of Cu(I). In addition, the catalyst also has good selectivity for N-2 to NH3.
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