4.6 Article

Long-Range Chiral Induction by a Fully Noncovalent Approach in Supramolecular Porphyrin-Calixarene Assemblies

期刊

CHEMISTRY-A EUROPEAN JOURNAL
卷 26, 期 16, 页码 3515-3518

出版社

WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.202000126

关键词

calixarenes; chirality induction; circular dichroism; noncovalent interactions; porphyrinoids

资金

  1. University of Catania, Department of Chemical Sciences (Piano per la Ricerca 2016-2018-Linea Intervento 2)
  2. Ministero della Istruzione, dell'Universita e della Ricerca (MIUR) PRIN [2017YJMPZN]

向作者/读者索取更多资源

The hierarchical assembly, in aqueous solution, of a new multi-metalloporphyrin/calixarene aggregate has been accomplished. In this supramolecular system transfer of chirality, from the outermost components to the central porphyrin reporter, takes place as a result of favorable and fully noncovalent long-range electronic communication.

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