期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 26, 期 14, 页码 3129-3136出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201904948
关键词
dynamic libraries; electrochemistry; metathesis; mixed disulfides; sulfur
A novel approach of electrolysis using alternating current was applied in the sulfur-sulfur bond metathesis of symmetrical disulfides towards unsymmetrical disulfides. As initially expected, a statistical distribution in disulfides was obtained. Furthermore, the influence of electrode polarisation by alternating current was investigated on a two-disulfide matrix. The highly dynamic nature of this chemistry resulted in the creation of dynamic disulfide libraries by expansion of the matrices, consisting of up to six symmetrical disulfides. In addition, mixing of matrices and stepwise expanding of a matrix by using alternating current electrolysis were realised.
作者
我是这篇论文的作者
点击您的名字以认领此论文并将其添加到您的个人资料中。
推荐
暂无数据