期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 26, 期 10, 页码 2138-2142出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201904502
关键词
amination; amines; ethylene; hydroaminoalkylation; titanium
资金
- Research Training Group Chemical Bond Activation [GRK 2226]
- Deutsche Forschungsgemeinschaft
The first examples of titanium-catalyzed hydroaminoalkylation reactions of ethylene with secondary amines are presented. The reactions can be achieved with various titanium catalysts and they do not require the use of high pressure equipment. In addition, the first solid-state structure of a titanapyrrolidine that is formed by insertion of an alkene into the Ti-C bond of a titanaaziridine is reported.
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