期刊
CHEMISTRY-A EUROPEAN JOURNAL
卷 26, 期 26, 页码 5818-5823出版社
WILEY-V C H VERLAG GMBH
DOI: 10.1002/chem.201905311
关键词
anode materials; antimony; energy storage; potassium-ion batteries; restriction structure
资金
- China Postdoctoral Science Foundation [2016M601395]
Sb-based materials have attracted much attention owing to their ability to undergo a multi-electron alloy reaction with K+. However, there are still the serious problems of volume change and aggregation of particles, which lead to rapid capacity fading and a limited lifespan. In this work, a graphene/amorphous carbon restriction structure is proposed, in which the amorphous carbon layer on the surface of Sb nanoparticles can protect the particles from pulverization, and the graphene can buffer the volume change of the material. In addition, the conductive network formed by the dual carbon structure effectively improves the rate performance of the material. Thus, the material delivers a high capacity of 550 mA h g(-1) at 100 mA g(-1), a rate capability of 370 mA h g(-1) at 2000 mA g(-1), and a long lifespan of 350 cycles without significant capacity fading. The dual carbon strategy proposed offers a reference for the design of high-performance anode materials.
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