期刊
CHEMISTRY OF MATERIALS
卷 32, 期 7, 页码 3288-3296出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemmater.0c00609
关键词
-
资金
- National Natural Science Foundation of China [51890862, 51472251, 61675212]
Herein, we offer a simple but crucial case for rational design and syntheses of infrared nonlinear optical (NLO) materials by employing state-of-the-art AgGaS2 as a parent model. On the basis of inheriting structural advantages of AgGaS2, an as-grown CuZnPS4 crystal exhibits a sharply enlarged energy gap (3.0 eV) benefiting from the cosubstitution of Ag with lighter Cu/Zn. Remarkably, the valence electron distribution of CuZnPS4 is optimized by bringing in cation vacancy defects, which significantly reinforce the second harmonic generation (SHG) (3 X AgGaS2) and compensate for the adverse effect of band gap enlargement. Careful experimental and theoretical investigations illustrate that CuZnPS4 strikes a desirable balance among a strong SHG response, good phase matchability, large band gap, high laser damage threshold, outstanding physicochemical stability, low melting point, and cost-effective but non- toxic composition, which might shed light on follow-up design and exploratory synthesis of NLO materials.
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