期刊
CHEMISTRY LETTERS
卷 49, 期 3, 页码 295-298出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.190903
关键词
Dual hydrogen bonding intramolecular bridge; Through-space-couplings; Acenaphthenediol
资金
- Koyanagi Foundation
- Tokyo Ohka Foundation for the Promotion of Science and Technology
- Ogasawara Foundation for the Science and Engineering
Dual hydrogen bonding intramolecular bridge pivoted by fluoro group for 1,2-bis(2-fluorophenyl)-3,8-dimethoxyacenaphthenediol in solution is ascertained as simultaneous contribution of mutual fluoro group demonstrated by tangible through-space-couplings in H-1 and F-19 NMR. The shared fluorine atom inside non-coplanarly accumulated aromatic rings molecule adopts quite adequate position free from interfering solvation to interact with two intramolecular hydrogen atoms prior to stronger hydrogen-accepting oxygen atoms nearby so that essentially weak fluorine-concerning non-classical and classical hydrogen bonds fix reinforcingly intramolecular spatial organization.
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