期刊
CHEMISTRY LETTERS
卷 49, 期 1, 页码 28-53出版社
CHEMICAL SOC JAPAN
DOI: 10.1246/cl.190731
关键词
Metal-organic cages (MOCs); Extended networks; Cage-to-framework
资金
- Strategic Priority Research Program of CAS [XDB20000000]
- Key Research Program of Frontier Sciences, CAS [QYZDB-SSW-SLH019]
- CAS-TWAS President's Fellowship for International Doctoral Students
- National Nature Science Foundation of China [21771177, 51603206]
Metal-organic cages (MOCs) represent a tantalizing class of metal-organic materials (MOMs) in terms of host-guest binding ability related to their well-defined cavities and engineered pores. Herein, we highlight the synthesis of MOCs and their post-assembly modification (PAM) reactions. Unlike discrete MOCs, infinite cage-based frameworks that use MOCs as supramolecular building blocks (SBBs) will be discussed. Finally, we address the solubility and stability of MOCs as significant prerequisites for favoring the high-order assembly into extended structures.
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