期刊
CHEMICAL REVIEWS
卷 120, 期 6, 页码 3161-3209出版社
AMER CHEMICAL SOC
DOI: 10.1021/acs.chemrev.9b00408
关键词
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资金
- Natural Sciences and Engineering Research Council of Canada [RGPIN-2016-03778]
- Canadian Institutes of Health Research [FDN-148381, 201312MSH-322191-209186]
- Michael Smith Foundation for Health Research [16776]
Natural nonproteinogenic amino acids vastly outnumber the well-known 22 proteinogenic amino acids. Such amino acids are generated in specialized metabolic pathways. In these pathways, diverse biosynthetic transformations, ranging from isomerizations to the stereospecific functionalization of C-H bonds, are employed to generate structural diversity. The resulting nonproteinogenic amino acids can be integrated into more complex natural products. Here we review recently discovered biosynthetic routes to freestanding nonproteinogenic alpha-amino acids, with an emphasis on work reported between 2013 and mid-2019.
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