期刊
CHEMICAL ENGINEERING JOURNAL
卷 382, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.122797
关键词
Co1.29Ni1.71O4; Oxygen vacancy; EM wave absorption properties; Defect polarization
资金
- National Science Foundation of China [21806129, 51872238]
- Fundamental Research Funds for the Central Universities [3102018zy045, 3102019AX11]
- Natural Science Basic Research Plan in Shaanxi Province of China [2017JQ5116]
Novel binary cobalt nickel oxide Co1.29Ni1.71O4 hollowed-out spheres have been successfully synthesized via a facile hydrothermal method with a further calcination process. The phase, crystal structure, morphology, and electromagnetic (EM) and EM wave absorption properties were characterized in detail. We find that as the temperature increases, the ionic mobility in the spinel structure will increase, leading to lattice disorder and an increase in the concentration of oxygen vacancy, which will improve the dielectric loss and EM wave absorption capacity of the material. The minimum reflection loss (RLmin) of the sample calcined at 500 degrees C reached up to -50.7 dB with a matching thickness (d) of 1.6 mm, and the corresponding effective absorption bandwidth (f(E), RL < -10 dB) was 4.84 GHz. The sample calcined at 550 degrees C also showed excellent EM wave absorption properties, and the corresponding RLmin, f(E), and d were -44.5 dB, 5.13 GHz, and 2.0 mm, respectively. We are confident that the spinel Co1.29Ni1.71O4 will become an excellent candidate for a new generation of high-efficiency EM wave absorbing material.
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