期刊
CHEMICAL ENGINEERING JOURNAL
卷 382, 期 -, 页码 -出版社
ELSEVIER SCIENCE SA
DOI: 10.1016/j.cej.2019.122854
关键词
Li-O-2 batteries; Electrode; Interfacial engineering; 1T-MoS2; Palladium doping
资金
- National Natural Science Foundation of China [21905033]
- Science and Technology Department of Sichuan Province [2019YJ0503]
- Cultivating Program of Middle Aged Key Teachers of CDUT [KYGG201709]
Lacking strategy to enhance the intrinsic catalytic activity and site density of hexagonal molybdenum disulfide (2H-MoS2) is restricting their further development as viable electrocatalysts for lithium-oxygen (Li-O-2) battery. Here, palladium (Pd) induced metallic (1T) MoS2 nanosheet array supported on carbon textiles (Pd-TMS/CT) was deliberately fabricated as a high-efficient freestanding cathode of Li-O-2 battery. Transforming semi-conducting 2H phase to the stabilized metallic 1T phase of MoS2 was induced by doping Pd using a spontaneous interfacial redox strategy. This novel class of 1T-MoS2 nanosheet array with unique electronic structures enables the electrode with fast reaction kinetics, high electrical transport rate, and proliferated catalytic active sites, which lead to a striking improvement of their intrinsic catalytic behavior in Li-O-2 battery. In addition, the synergistic effect with well-designed surface chemistry of MoS2 is favorable for the reversible formation and decomposition of products and the inhibition of side reactions on Pd-TMS/CT cathode. As a result, the battery with Pd-TMS/CT exhibits outstanding electrochemical behavior in terms of high discharge capacity of 7441 mA h g(-1), low overpotential, and especially the excellent electrochemical stability for over 2488 h (622 cycles). Moreover, due to its flexibility superiority, the assembled pouch-type battery based on Pd-TMS/CT cathode can stably operate in real air atmosphere under different bending and twisting conditions, which opens up a variety of potential applications of flexible devices with high energy density.
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